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Furthermore, tetrahydrobiopterin (BH4), a cofactor for eNOS, was associated with improved vasodilation to acetylcholine in chronic smokers, but not tetrahydroneopterin (NH4), suggesting that reduced NO bioactivity in chronic smokers is partially caused by reduced BH4 availability and that NOS-mediated superoxide production is an important source of superoxide in chronic smokers 20)

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