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Metabolism and Bioavailability of Glucosinolates Metabolism The hydrolysis of glucosinolates, which is catalyzed by a class of enzymes called myrosinases (-thioglucosidases), leads to the formation of breakdown compounds, such as thiocyanates, isothiocyanates, indoles, oxazolidine-2-thiones (e.g., goitrin), epithionitrile, and nitrile ( Figure 2 )

The proteasome is part of the ubiquitin proteasome system (UPS), which is critical for protein quality control and is the main intracellular degradation pathway that eliminates polyubiquitinated misfolded and oxidized proteins by a multi-complex 26 S proteasome 16,17,24,40

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