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Labelled precursor feeding studies indicate that 2 undergoes C6-reduction and decarboxylation to yield the unusual nucleophile 1,2-dihydropyridine ( 4a ), which reacts at C3 with the electrophilic iminium 3 to form 3,6-dihydronicotine ( 5a ) followed by stereoselective removal of the C6-hydrogen to form 1 (Fig

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What he lacked in raw talent, he made up for with the fiercely competitive nature that distinguished his athletic career